Applications of In Situ Mossbauer Effect Spectroscopy to the Study of Electrode-Electrolyte Interfaces

摘要

Mossbauer effort spectroscopy has emerged as a powerful tool in the in situ examination and analysis of the physico-chemical properties of active nuclei containing species either adsorbed at solid-liquid interfaces or present in layers on electrode surfaces. Applications are given for in situ Mossbauer in emission and transmission modes as well as illustration of the newly developed in situ electron conversion Mossbauer spectroscopy. Several aspects of the experimental technique are discussed and the literature in the area is reviewed. (Author)