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Transition-Metal-Promoted Reactions of Boron Hydrides. 8. Nickel-Promoted Alkyne Insertion Reactions: A New Synthesis of the Four-Carbon Carborane nido-4,5,7,8-R4C4B4B4H4

机译：过渡金属促进的氢化硼反应。 8.镍促进的炔烃插入反应：四碳碳硼烷nido-4,5,7,8-R4C4B4B4H4的新合成

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A new type of metal-promoted alkyne/poly-hedral borane insertion reaction is reported. The reaction of the carborane nido-2,3-Et2C2B4H6 with 2-butyne in the presence of sodium hydride and nickel(II) chloride has been found to result in a two-carbon insertion into the cage system to produce the tetracarbon carborane nido-4,57,8-Me2Et2C4B4H4.

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Mirabelli, M. G.; Sneddon, L. G.;
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年度 1986
页码 p.1-3
总页数 3
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Boron hydrides; Hydrides; Nickel intermetallics; Synthesis(Chemistry); Carboranes; Sodium; Reprints;

机译：硼氢化物;氢化物;镍金属间化合物;合成（化学）;碳硼烷;钠;重印;

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机译：通过硼插入反应合成邻3-和间-2-取代的碳硼烷并进行表征，包括双插入反应产物的结构
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机译：多面体硼化合物与碳水化合物的缀合物8.〜*含有1至3个β-乳糖苷胺残基的正-邻-甲碳烷糖共轭物的合成与性质
3. Reactions of Icosahedral Carboranes with Iminotris(dimethylamino)Phosphorane HNP(NMe2)3: a Deboronation Intermediate nido-C2B10H12·N(H)P(NMe2)3, Deboronation Reactions and Hydrogen-bonded Closo-carborane Systems [J] . Andrei S. Batsanov, Royston C.B. Copley, Matthew G. Davidson, Journal of Cluster Science . 2006,第1期

机译：二十面体碳硼烷与亚氨基三（二甲氨基）膦HNP（NMe2 ）3 的反应：脱硼中间体nido-C2 B10 H12 ·N（H）P （NMe2 ）3 ，脱硼反应和氢键结合的碳氢烷系统
4. Synthesis and Alkyne-insertion Reactions of Silyl(germyl)-and Germyl(stannyl)platinum(II)Complexes [C] . Takashi Sagawa, Fumiyuki Ozawa Symposium on Organometallic Chemistry . 2003

机译：甲硅烷基（盐酸）-Andsmyl（叔尼烷基）铂（II）复合物的合成和炔烃插入反应
5. Synthesis of conjugates of L-fucose and ortho-carborane as potential agents for boron neutron capture therapy, and, Synthesis of 2,3-dideoxy-2,3-methanoribofuranoside glycosyl donors and a study of their use in stereocontrolled glycosylation reactions. [D] . Basak, Prakriti. 2003

机译：合成L-岩藻糖和邻位碳硼烷作为硼中子俘获治疗的潜在药物，以及2,3-二脱氧-2,3-甲基呋喃呋喃糖苷糖基供体的合成及其在立体控制糖基化反应中的应用研究。
6. Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules [O] . Yoshiaki Shoji, Naoki Tanaka, Sho Muranaka, -1

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7. Reactivity of Ortho-Palladated Phenol Derivatives with Unsaturated Molecules. 1. Insertion of CO, Isocyanides, Alkenes, and Alkynes. CO/Alkene, Alkyne/Isocyanide, and Isocyanide/Alkene Sequential Insertion Reactions [O] . -1

机译：用不饱和分子的邻钯苯酚衍生物的反应性。 1.插入CO，异氰酸酯，烯烃和炔烃。 Co /烷烃，炔/异氰化物，和异氰化物/烯烃顺序插入反应
8. Transition-Metal-Promoted Reactions of Boron Hydrides. 7. Platinum(II) Bromide Catalyzed Cage Growth and Dehydrocoupling Reactions of Diborane with Small Polyhedral Carboranes and Boranes: Synthesis of a New Arachno Carborane, 5,6-C2B6H12, and the Diborane-Coupled Compounds 2:1', 2'-(1,6-C2B4H5)(B2H5) and 2:1',2'-(B5H8)(B2H5). [R] . Corcoran, E. W., Sneddon, L. G. 1985

机译：过渡金属促进的氢化硼反应。 7.铂（II）溴化物催化的笼型生长和乙硼烷与小多面体碳硼烷和硼烷的脱氢偶联反应：合成新的arachno Carborane，5,6-C2B6H12和乙硼烷偶联化合物2：1'，2' - （ 1,6-C2B4H5）（B2H5）和2：1'，2' - （B5H8）（B2H5）。

Transition-Metal-Promoted Reactions of Boron Hydrides. 8. Nickel-Promoted Alkyne Insertion Reactions: A New Synthesis of the Four-Carbon Carborane nido-4,5,7,8-R4C4B4B4H4

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