Synthesis, Characterization and Structural Studies of In(C5H4Me) by X-Ray Diffraction and Electron Diffraction Techniques and a Reinvestigation of the Crystalline State of In(C5H5) by X-Ray Diffraction Studies

摘要

The compound In(C5H4Me) has been prepared from InC1 and Li(C5H4Me) in diethyl ether and fully characterized according to its physical and solubility properties, reaction with dilute HC1, a cryoscopic molecular weight study in cyclohexane, infrared and 1H NMR spectroscopic properties, an X ray structural study and a gas-phase electron diffraction study. In addition, a quantitative X ray structural study has been used to reinvestigate the nature of the solid state of In(C5H5). The compound In(C5H4Me) crystallizes in the centrosymmetric space group P21/n (N0. 14var) with a = 6.1636(14), b = 11.5684(17), c = 9.1723(15)A, beta = 103.561(15), V = 635.78(19)A3 and Z = 4. Organoindium chemistry, Indium compounds, Chemistry, X ray structural studies, Electron diffraction studies, Cyclopentadienyl.