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Heterophasic Isotope Exchange in Nanoscale Metal Oxide Particles. Lattice Oxygenand Surface OH Groups with Water Vapor (D2O and H2 Oxygen 18)

机译：纳米金属氧化物颗粒中的异相同位素交换。具有水蒸气的晶格氧和表面OH基团（D2O和H2氧气18）

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Ionic solids MgO, CaO, and Fe2O3 exchange surface and lattice oxide anions withH2 180 as monitored by pulsed reactor-GC-MS studies. Depending on the temperature, the process can be controlled to exchange only OH, or additional

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Li, Y. X.; Klabunde, K. J.;
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年度 1992
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总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Isotope exchange; Water vapor; Acids; Activation; Activation energy; Adsorption; Anions; Decomposition; Diffusion; Energy; Exchange; Formic acid; Isotopes; Layers; Oxides; Particle size; Particles; Solids; Surfaces; Synthesis; Temperature; Ultrafines; Wat;

机译：同位素交换;水蒸气;酸;活化;活化能;吸附;阴离子;分解;扩散;能量;交换;甲酸;同位素;层;氧化物;粒径;颗粒;固体;表面;合成;温度;超细; Wat;

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1. Water Oxidation by Photosystem II: H2O−D2O Exchange and the Influence of pH Support Formation of an Intermediate by Removal of a Proton before Dioxygen Creation [J] . Lszl Gerencsr and Holger Dau Biochemistry . 2010,第47期

机译：光系统II的水氧化：H2O-D2O交换以及通过在生成双氧之前除去质子而形成的中间体对pH的影响
2. Surface oxygen dynamics and H-2 oxidation on cobalt spinel surface probed by O-18/O-16 isotopic exchange and accounted for by DFT molecular modeling: facile interfacial oxygen atoms flipping through transient peroxy intermediate [J] . Zasada Filip, Janas Janusz, Piskorz Witold, Research on Chemical Intermediates . 2017,第5期

机译：O-18 / O-16同位素交换探测的钴尖晶石表面上的表面氧动力学和H-2氧化，并通过DFT分子建模占：通过瞬时过氧中间体翻转的容易界面氧原子
3. Distribution of isotopic water molecules, H2O, HDO, and D2O, in vapor and liquid phases in pure water and aqueous solution systems [J] . Kakiuchi M. Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society . 2000,第9期

机译：在纯水和水溶液系统中，气相和液相中的同位素水分子H2O，HDO和D2O的分布
4. Comparative determination of surface and lattice oxygen mobility on vanadium phosphorus oxides by isotopic exchange with C~(18)O_2 [C] . B. Bachiller-Baeza, I. Rodrlguez-Ramos, J. C. Volta, International Conference on Spillover . 2001

机译：通过同位素交换与C〜（18）O_2对磷氧化物钒磷氧气对表面和晶格氧迁移率的比较测定
5. Oxygen isotopic fractionation in carbon dioxide-laser microprobes: Testing the metal oxide-metal fluoride chemical and isotopic exchange hypothesis. [D] . Johnson, Timothy Whipple. 2001

机译：二氧化碳激光微探针中的氧同位素分馏：测试金属氧化物-金属氟化物化学和同位素交换假说。
6. Isotopic (18O) shift in 31P nuclear magnetic resonance applied to a study of enzyme-catalyzed phosphate—phosphate exchange and phosphate (oxygen)—water exchange reactions [O] . Mildred Cohn, Angela Hu 1978

机译：同位素（18O）在31P核磁共振中的位移应用于酶催化的磷酸盐-磷酸盐交换和磷酸盐（氧气）-水交换反应的研究
7. Surface oxygen dynamics and H2 oxidation on cobalt spinel surface probed by 18O/16O isotopic exchange and accounted for by DFT molecular modeling: facile interfacial oxygen atoms flipping through transient peroxy intermediate [O] . Filip Zasada, Janusz Janas, Witold Piskorz, 2016

机译：通过18O / 16O同位素交换探测并通过DFT分子建模解释了钴尖晶石表面的表面氧动力学和H2氧化：界面易发生的氧原子通过瞬态过氧中间体翻转

Heterophasic Isotope Exchange in Nanoscale Metal Oxide Particles. Lattice Oxygenand Surface OH Groups with Water Vapor (D2O and H2 Oxygen 18)

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