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Synthesis of Polyphenylenes via Bergman Cyclization of Enediyne Monomers

机译：烯二炔单体伯格曼环化合成聚苯

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摘要

Described is the synthesis of polyphenylenes via the Bergman cyclization ofenediyne monomers. These monomers were synthesized via the Stephans-Castro/Sonogashira reaction and polymerized under varying conditions.

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作者
Tour, J. M.; John, J. A.;
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年度 1993
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总页数 7
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Monomers; Polyphenylenes; Synthesis; Thermal cycling tests; Benzene; Chemicalradicals;

机译：单体;聚苯;合成;热循环试验;苯;化学自由基;

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专利

1. Co-sensitization of N719 with polyphenylenes from the Bergman cyclization of maleimide-based enediynes for dye-sensitized solar cells [J] . Dong Luhua, Zheng Zhiwei, Wang Youfu, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2015,第21期

机译：染料敏化太阳能电池中马来酰亚胺基烯二炔的Bergman环化作用使N719与聚亚苯基共敏化
2. SYNTHESIS OF POLYPHENYLENE DERIVATIVES BY THERMOLYSIS OF ENEDIYNES AND DIALKYNYLAROMATIC MONOMERS [J] . John JA., Tour JM. Tetrahedron . 1997,第45期

机译：烯和二乙炔基芳香族单体的热解法合成聚乙烯衍生物
3. Tuning the Bergman Cyclization by Introduction of Metal Fragments at Various Positions of the Enediyne. Metalla-Bergman Cyclizations [J] . Edyta M. Brzostowska, Roald Hoffmann, Carol A. Parish Journal of the American Chemical Society . 2007,第14期

机译：通过在对映体的不同位置引入金属碎片来调节Bergman环化。 Metalla-Bergman环化
4. Towards Photoswitchable Enediyne Antitumor Antibiotics: Design, Synthesis, Photochemistry and Cycloaromatization of Prototype Enediynes [C] . A. Poloukhtine, D. Pandithavidana, G. Karpov European Symposium on Organic Chemistry . 2009

机译：朝向光学性enediyne抗肿瘤抗生素：原型Enediynes的设计，合成，光化学和聚环化
5. Studies towards tandem "one-way" Bergman radical cyclizations of aromatic enediynes and synthesis of anti-1,3-diols by the cationic coupling of nucleophiles with 4-acetoxy-1,3-dioxanes. [D] . Powell, Noel Aaron. 1998

机译：通过亲核试剂与4-乙酰氧基-1,3-二恶烷的阳离子偶联，对芳香烯二炔进行串联“单向” Bergman自由基环化和合成抗1,3-二醇的研究。
6. Efficient and Accurate Characterization of the Bergman Cyclization for Several Enediynes Including an Expanded Substructure of Esperamicin A1 [O] . Edward C. Sherer, Karl N. Kirschner, Frank C. Pickard IV, -1

机译：有效和准确的表征包括环孢霉素A1扩展亚结构的几个烯类的Bergman环化。
7. Effect of Remote Trigonal Carbons on the Kinetics of Bergman Cyclization: Synthesis and Chemical Reactivity of Pyridazinedione-Based Enediynes [O] . -1

机译：远程三角碳对贝格曼环化动力学的影响：吡吡嗪型enediynes的合成与化学反应性

Synthesis of Polyphenylenes via Bergman Cyclization of Enediyne Monomers

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