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Exclusive Beta-Hydrosilylation of Acrylates Catalyzed by Copper-Tetramethylethylenediamine

机译：铜 - 四甲基乙二胺催化丙烯酸酯的独特β-氢化硅烷化反应

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摘要

Trichlorosilane and methyldichlorosilane react with methyl and ethyl acrylate togive high yields of only the beta adduct in the presence of copper salts and tetramethylethylenediamine.

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作者
Boudjouk, P.; Kloos, S.; Rajkumar, A. B.;
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年度 1993
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总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Acrylates; Catalysis; Reprints; Copper; Chlorosilanes; Methyl radicals; Ethyl radicals; Salts; Ethylenediamine; Silicon; Olefin polymers; Chemical bonds; Silanes;

机译：丙烯酸酯;催化;重印;铜;氯硅烷;甲基;乙基;盐;乙二胺;硅;烯烃聚合物;化学键;硅烷;

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专利

1. A new catalyst for exclusive beta-hydrosilylation of acrylonitrile [J] . Chauhan M., Boudjouk P., Chauhan BPS. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第22期

机译：一种新型的丙烯腈独家β-氢化硅烷化催化剂
2. Ultrafast synthesis of poly(methyl acrylate) and poly(methyl acrylate)-b-poly(vinyl chloride)-b-poly(methyl acrylate) by the Cu(0)/tris(2-dimethylaminoethyl)amine-catalyzed living radical polymerization and block copolymerization of methyl acrylate i [J] . Percec V, Guliashvili T, Popov AV Journal of Polymer Science, Part A. Polymer Chemistry . 2005,第9期

机译：通过Cu（0）/三（2-二甲基氨基乙基）胺催化的活性自由基聚合和超快合成聚丙烯酸酯和聚丙烯酸甲酯-b-聚氯乙烯-b-丙烯酸甲酯丙烯酸甲酯的嵌段共聚反应
3. B(C6F5)3-Catalyzed Group Transfer Polymerization of Acrylates Using Hydrosilane: Polymerization Mechanism, Applicable Monomers, and Synthesis of Well-Defined Acrylate Polymers [J] . Chen Yougen, Jia Qun, Ding Yuansheng, Macromolecules . 2019,第3期

机译：B（C6F5）3催化的丙烯酸酯的丙烯酸酯的基团转移聚合：聚合机理，适用的单体，以及合成明确限定的丙烯酸酯聚合物
4. Synthesis of Substituted 2,2'-Bipyridines by Cobalt-Catalyzed Cycloaddition Reactions of Nitriles and 1,6-Diynes with Exclusive Regioselectivity [C] . Taichi Ito, Avijit Goswami, Kazuhiko Ohtaki Symposium on Organometallic Chemistry . 2007

机译：用腈钴催化的环加成反应合成腈和1,6-迪杨的钴催化的循环加油反应
5. Organocatalytic, Michael-Stetter reaction and rhodium(I)-catalyzed hydroheteroarylation of acrylates with benzoxazoles: Reaction development and investigations into origins of enantioselectivity [D] . Filloux, Claire M. 2015

机译：丙烯酸酯与苯并恶唑的有机催化，Michael-Stetter反应和铑（I）催化的加氢杂芳基化：反应发展和对映选择性的起源研究
6. Density Functional Theory Study on the Mechanism ofIridium-Catalyzed Benzylamine ortho C–H Alkenylationwith Ethyl Acrylate [O] . Jiarong Wang, Baoping Ling, Peng Liu, 2020

机译：密度泛函理论的机理研究铱催化的苄胺邻位CH链烯基化与丙烯酸乙酯
7. Copolymers incorporated with β-substituted acrylate synthesized by organo-catalyzed group-transfer polymerization [O] . Motosuke Imada, Yasumasa Takenaka, Takeharu Tsuge, 2021

机译：掺入通过有机催化基团转移聚合合成的β-取代的丙烯酸酯的共聚物
8. New Catalyst for the Efficient and Selective Beta-Hydrosilylation of Acrylonitrile. Effect of Ultrasound [R] . Rajkumar, A. B., Boudjouk, P. 1989

机译：丙烯腈高效选择性β-氢化硅烷化的新催化剂。超声波的影响

Exclusive Beta-Hydrosilylation of Acrylates Catalyzed by Copper-Tetramethylethylenediamine

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