Ligand Hyperfine Coupling in Mo(V)Oxyhalide Complexes

摘要

For a series of Mo(V)oxyhalide complexes(MoOL5)2-(L = F,Cl,Br,I),interpretation of the ligand hyperfine coupling parameters(A~L tensor components)is considered.The role of spin polarization is elucidated and the effect of charge transfer states is taken into account.The A~L tensor components were calculated using the covalency parameters derived from experimental EPR and optical spectroscopy data for compounds under study(inverse problem of EPR spectroscopy).