Preparation of self-reinforcement of porous mullite ceramics through in situ synthesis of mullite whisker in flyash body

摘要

Self-reinforced porous mullite ceramics were fabricated by a starch consolidation method with flyash, different aluminium sources (Al(OH)_3 and Al_2O_3) and the additive AlF_3 as raw materials. The reinforcement mechanism of needle-like mullite whiskers through in situ synthesis in ceramic body was investigated. The bulk density, apparent porosity and bending strength of the samples were tested. Phase compositions and microstructures of the sintered samples were measured by XRD and SEM, respectively. It showed that AlF_3 as additive was helpful to the formation of mullite whiskers at a low temperature. As the aluminium sources, Al(OH)_3 was more suitable for the preparation of mullite whiskers than Al_2O_3. The in situ synthesized mullite whiskers formed an interlocking structure, which enhanced the mechanical strength of the porous mullite ceramics. Porous mullite ceramics with bending strength of about 100 MPa and apparent porosity of about 55% were made at 1550 °C.