Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-H aminations

Reddy RP; Davies HML

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Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-H aminations

机译：金刚烷基甘氨酸衍生的四羧酸二吡啶酯作为手性催化剂，用于对映选择性C-H胺化

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摘要

The dirhodium tetracarboxylate, Rh-2(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations.

机译：衍生自金刚烷基甘氨酸的四羧酸dirhodium Rh-2（S-TCPTAD）（4）是分子间和分子内C-H胺化的有效手性催化剂。

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《Organic letters》 |2006年第22期|共4页
作者
Reddy RP; Davies HML;
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正文语种 eng
中图分类有机化学;
关键词
NITROGEN-ATOM-TRANSFER; MANGANESE PORPHYRINS; OXIDATIVE FUNCTIONALIZATION; ASYMMETRIC AZIRIDINATION; BOND FUNCTIONALIZATION; AMIDATION; COMPLEXES; RUTHENIUM; INSERTIONS; HYDROXYLATION;

机译：氮原子转移;锰卟啉;氧化功能;非对称叠氮化;键合功能;酰胺化;络合物;钌;插入;羟基化;

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专利

1. Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-H aminations [J] . Reddy RP, Davies HML Organic letters . 2006,第22期

机译：金刚烷基甘氨酸衍生的四羧酸二铱盐作为手性催化剂，用于对映选择性C-H胺化
2. Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions [J] . Reddy RP, Lee GH, Davies HML Organic letters . 2006,第16期

机译：金刚烷基甘氨酸衍生的四羧酸二铱盐作为手性类化合物的手性催化剂
3. Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions [J] . Reddy RP, Lee GH, Davies HML Organic letters . 2006,第16期

机译：金刚烷基甘氨酸衍生的四羧酸二铱盐作为手性类化合物的手性催化剂
4. Chiral dirhodium catalysts confined in porous hosts [C] . H.M. Hultman, M. de Lang, M. Nowotny, 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts, Sep 9-12, 2002, Louvain-la-Neuve, Belgium . 2002

机译：封闭在多孔主体中的手性dirhodium催化剂
5. Enantioselective Transformations of α- and β-Amino C-H Bonds Promoted by Cooperative Actions of Achiral and Chiral Lewis Acid Catalysts [D] . Chang, Yejin. 2021

机译：α-和β-氨基C-H键的对映选择性转化，促进了成立和手性路易斯酸催化剂的合作作用
6. A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C—H Amination [O] . David N. Zalatan, J. Du Bois -1

机译：手性氨基甲酸铑催化对映选择性的C-H胺化反应
7. Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid Reactions [O] . -1

机译：衍生自亚马氨基甘氨酸的甲酸钠作为甲壳素反应的手性催化剂

Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-H aminations

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