Electrosynthesis of esters of mono-and dioxoalkanoic and alkanedioic acids on the basis of nitro-substituted alkyl carboxylates and cycloalkanones

摘要

A one-pot electrochemical method for the synthesis of methyl monooxoalkanoates with the carbonyl group in position 4, methyl dioxoalkanoates with the oxo groups in positions 4,7-, 6,9-, 7,10-, and 12, 15, and methyl 4-oxoalkanedioates was developed. This method is based on amperostatic electrolysis is an undivided cell of the salts of esters of nitroalkanoic acids and their adducts with CH_2 = CHX (X = Ac, CO_2Me).