4-Phenyl-1-(1R,4R)-1,7,7-tri­methyl-2-oxobi­cyclo2.2.1heptan-3-yl­­idenehydrazinecarbo­thio­amide

摘要

In the title compound, C17H21N3OS common nomenclature: (R)-camphor 4-phenylthiosemicarbazone, the N—N—C—(S)—N fragment deviates slightly from planarity, with a maximum deviation of 0.0259 (12) A˚ for the hydrazinic N atom, and makes an angle of 29.55 (0) with the aromatic ring. The molecular structure is stabilized by an intramolecular N—HO hydrogen bond and a short N—HN interaction with graph-set motifs S(6) and S(5), respectively. In the crystal, the centrosymmetric arrangement of the molecules resembles a herringbone packing motif along 001. As a result of the steric effects of the camphor entity, an apolar organic periphery and the intramolecular nature of the hydrogen bonds, neither strong nor relevant intermolecular interactions are observed.