Synthesis and Crystal Structure of Tris(l,3-diphenyl-l,3-propanedionato)Titanium(III)

摘要

Group 4 metal derivatives are receiving increased attention on account of their potential applications in various areas of technology and model studies of synthetic and catalytic chemistry.And the molecular structures and properties of titanium complexes of beta-diketonates are of great interest in both experimental and theoretical respects.Recently,we have investigated the reactivities of [Cp_2M] (M=Ti,Zr) prepared from [Cp_2TiM] and 2n-BuLi with beta-diketone.