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首页> 外文期刊>journal of chemical physics >Decay of Correlations. II. Relaxation of Momentum Correlations and Momentum Distributions in Harmonic Oscillator Chains
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Decay of Correlations. II. Relaxation of Momentum Correlations and Momentum Distributions in Harmonic Oscillator Chains

机译:Decay of Correlations. II. Relaxation of Momentum Correlations and Momentum Distributions in Harmonic Oscillator Chains

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We have studied the relaxation of thenhyphen;particle momentum distribution functionfnlpar;pn; trpar;and the correspondingnhyphen;particle Ursell functionUnlpar;pn; trpar;for both an isolated infinite chain of coupled harmonic oscillators and an infinite chain of coupled harmonic oscillators in contact with a heat bath. The time development of the Ursell function gives us the desired information on the decay of initial momentum correlations. For both of these systems we have found the asymptotic relaxation lawsfnlpar;pn; trpar;thinsp;minus;thinsp;fnlpar;0rpar;lpar;pnrpar;thinsp;sim;thinsp;f1lpar;p; trpar;thinsp;minus;thinsp;f1lpar;0rpar;lpar;prpar;andUnlpar;pn; trpar;rarr;0aslsqb;f1lpar;p; trpar;thinsp;minus;thinsp;f1lpar;0rpar;lpar;prpar;rsqb;n, where the superscript zero denotes the equilibrium distribution. The momentum correlation functionUnlpar;pn; trpar;thus goes to zero (no correlations) much more rapidly than thenhyphen;particle distribution function approaches its equilibrium value. These results are identical with those obtained by us previously for initially correlated,noninteractingmanyhyphen;particle systems in contact with a heat bath and by Glauber for the relaxation of spins in an Ising lattice. It is interesting to speculate on the reason for this identity of results in such apparently different relaxation models, but no answer can be provided as yet.

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