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首页> 外文期刊>journal of chemical physics >An alternative to the magnus expansion in timehyphen;dependent perturbation theory
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An alternative to the magnus expansion in timehyphen;dependent perturbation theory

机译:An alternative to the magnus expansion in timehyphen;dependent perturbation theory

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摘要

An alternative to the Magnus expansion in timehyphen;dependent quantum mechanical perturbation theory is presented. An exponential form of the timehyphen;development operator, given as the exponential of a sum of products of integrals well known in timehyphen;dependent quantum mechanics, is derived from the standard perturbation expansion. The derivation is simple and the form of the terms in the exponential is so straightforward that theNth order term can be written by inspection. The standard Magnus terms can be obtained by rearrangement of the terms of the new expansion probably easier than they can be obtained by iteration of the original equations. A proof by induction is presented to establish the form of theNth term and it is shown how the new expansion terms relate to the Magnus terms. Some apparent differences between Magnus terms in the literature are resolved.

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