GermaniumL2,3M4,5M4,5andL2,3M2,3M4,5Auger spectra of volatile germanium compounds

摘要

GermaniumL2,3M2,3M4,5andL2,3M4,5M4,5Auger spectra excited by AlKagr;1,2radiation were measured for GeH4, GeF4, GeCl4, Ge(CH3)4, and Ge(C2H5)4. Energies and intensities were calculated by theoretical models based on a mixed coupling scheme usingjjcoupling for the initial state and LS coupling for the final state. Relaxation contributions have been evaluated and shown to vary qualitatively with the polarizabilities of the molecule.