Water Cluster Formation Rates of NOplus;in He, Ar, N2, and O2at 296deg;K

摘要

Reaction rates of NOplus;and its hydrates,NOplus;middot; nH2Olpar;nequals;1ndash;3rpar;, with water were measured in a flow system. The mechanism for conversion of NOplus;hydrates to H3Oplus;hydrates was confirmed, and rate constants for the sequence of six clustering, redissociation, and rearrangement reactions were determined for each of the four carrier gases He, Ar, N2, and O2.