Molecular jet study of the solvation of toluene by methane, ethane, and propane@fa@f)

摘要

Two color time of flight mass spectroscopy studies of toluene solvated by methane, ethane, and propane in a supersonic molecular jet have been carried out. This work is quite similar to the studies in the preceding paper on benzene. The conclusions and finding in the benzene investigation are strengthened and elaborated. The comparison of calculations and experiments has yielded information on binding enegy, geometry, and spectral shift. A strong correlation is found between observed cluster transition intensity and cluster nucleation processes and a tentative nucleation scheme for the molecular jet formation of solutendash;solvent clusters is presented.