Theoretical results obtained with the extended reference interaction site (XRISM) formalism are presented for sitendash;site solute solvent correlations and solutendash;solute potentials of mean force for infinitely dilute polar molecular solutes in various polar solvents. The standard RISM sitendash;site Ornsteinndash;Zernike like equations, in a Coulomb renormalized form, with a hypernetted chain (HNC) analog closure are used to derive results for polar molecular solutes in polar molecular solvents. For a dipolar diatomic solute the difference in the solvation behavior between atomic and molecular solvents is examined. Finite concentration results are compared with the infinite dilution intermolecular sitendash;site potentials of mean force for diatomic molecules in a simple fluid solvent.
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