AbstractData are presented on the second order Raman spectrum of rutile TiO2for various scattering geometries, at room and liquid N2temperatures. The results of a standard critical point analysis (i) allow the most important addition processes at low energies to be identified, (ii) indicate the importance of matrix element effects, and (iii) cannot account for a peak at 172 cm−1for theY(xy)Xgeometr
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