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Thermal Motion in Ice and Heavy Ice

机译:Thermal Motion in Ice and Heavy Ice

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摘要

Changes with temperature of xhyphen;ray intensities of the 00lreflections in ice and heavy ice are investigated. From these the amplitudes of thermal motion of oxygen and hydrogen atoms are determined separately. This can be accomplished since only hydrogen atoms contribute to the 004 reflection. The thermal amplitudes of the oxygen atoms, which represent molecular amplitudes, can be expressed in terms of a constant Debye characteristic temperature; 224deg;K for ordinary ice and 237deg;K for heavy ice. The amplitudes of thermal vibration of the hydrogen and deuterium atoms as derived from absolute intensities of 004 at various temperatures, cannot be expressed in terms of a characteristic temperature. They consist of superimposed stretching, bending and librational motions. In addition to these a rotational motion of low zero point energy seems to be present.

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