Friction Coefficient and Mobility Radius of Fractal-Like Aggregates in the Transition Regime

摘要

The influence of geometric properties and particle size on mobility properties of fractal-like aggregates was studied in the mass and momentum-transfer transition regimes. Two methodologies were investigated. The Collision Rate Method (CRM) that determines the slip correction factor through the ratio of two fictitious Brownian particle-aggregate effective collision rates, and the Adjusted Sphere Method (ASM) that assumes the existence of a virtual, flow-independent adjusted sphere with the same slip correction factor as the aggregate over the entire transition regime. The simulated fractal-like aggregates were synthetic as they were generated via a cluster-cluster agglomeration algorithm. The CRM was used to calculate the adjusted-sphere radius of various aggregates: we found it to be weakly dependent on the monomer Knudsen number for Kn greater than 0.5. Numerical expressions for the aggregate orientationally-averaged projected area and the adjusted-sphere radius are proposed. Both expressions depend on geometric, non-ensemble averaged quantities: the radius of gyration and the number of monomers. The slip correction factor and the mobility radius of DLCA and RLCA aggregates were calculated using the ASM: for a given number of monomers, fractal dimension and prefactor, and Knudsen number their values were approximately constant (averaged over aggregate realizations). A fractal-like scaling law based on the mobility radius was found to hold. The mobility fractal dimension and prefactor were determined for different aggregates. The hydrodynamic radius, proportional to the friction coefficient, and the dynamic shape factor of DLCA and RLCA aggregates were also calculated.