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Improvement in mechanical properties of NBR/AO60/MMT composites by surface hydrogen bond

机译:用表面氢键改善NBR / AO60 / MMT复合材料的力学性能

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Abstract >It is still a challenge to prepare high performance rubber/MMT composites by one‐pot method without solution. In this work, NBR/AO60/montmorillonite (MMT) (NBR/AM) composites were prepared by mechanical blending method and in‐situ formation of surface hydrogen bond was introduced under vulcanization process. Results showed that the polar parts of melting AO60 could partly intercalate into interlayer of MMT and some parts of melting AO60 molecules were absorbed onto surfaces of MMT particles during the vulcanization process. Subsequently, surface hydrogen bonds were constructed among NBR, AO60, and MMT after natural cooling, as evidenced by FTIR, resulting in more complex morphology and good interfacial adhesion in the NBR/AM composite. Consequently, as compared to NBR/montmorillonite (NBR/M) composite, remarkable improvements were found in mechanical properties and energy dissipation at high temperature of NBR/AM composite, which may provide a new prospect for designing high performance damping materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> >在没有解决方案的情况下,通过单壶方法制备高性能橡胶/ MMT复合材料仍然是一项挑战。在这项工作中,通过机械混合方法制备NBR / AO60 / montmorillonite(MMT)(NBR / AM)复合材料,并在硫化过程下引入表面氢键的原位形成。结果表明,熔融AO60的极性部分可以将晶体层中的晶间嵌入到MMT中,并且在硫化过程中,将熔融AO60分子的一些部分被吸收到MMT颗粒的表面上。随后,在天然冷却后,在NBR,AO60和MMT中构建表面氢键,如FTIR所证明的,导致NBR / AM复合材料中更复杂的形态和良好的界面粘附。因此,与NBR / MONTMORILLONITE(NBR / M)复合材料相比,在NBR / AM复合材料的高温下,在机械性能和能量耗散中发现了显着的改进,这可能为设计高性能阻尼材料提供新的前景。</ p > </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29566/'>《Polymer Composites》</a> <b style="margin: 0 2px;">|</b><span>2020年第6期</span><b style="margin: 0 2px;">|</b><span>共12页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7852.html" title="增强塑料、填充塑料">增强塑料、填充塑料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=composites&option=203" rel="nofollow">composites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hindered phenol&option=203" rel="nofollow">hindered phenol;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen bond&option=203" rel="nofollow">hydrogen bond;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=montmorillonite&option=203" rel="nofollow">montmorillonite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rubber&option=203" rel="nofollow">rubber;</a> </p> <div class="translation"> 机译:复合材料;阻尼苯酚;氢键;蒙脱石;橡胶; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023066532.html">Improvement in mechanical properties of NBR/AO60/MMT composites by surface hydrogen bond</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liang Ping&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liang Ping,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Shuyan&option=202" 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href="/journal-cn-9238/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 橡胶工业 </a> </span> <span> . 2006</span><span>,第007期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-24669_thesis/020221198128.html">OMMT /NBR 纳米复合材料的结构与性能研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=梁玉蓉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 梁玉蓉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谭英杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谭英杰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=丁亚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,丁亚</a> <span> <a href="/conference-cn-24669/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化工学会2006年年会暨全国第二届化工新材料学术技术报告会 </a> <span> <span> . 2006</span> </span> </div> </li> <li> <div> 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