Functional Kaolinite

Detellier Christian

摘要

Abstract >The world resources of all clays are extremely large. Among the various types of clays, the world mine production of kaolin in 2016 was 37.0?Mt, the largest mined clay. Kaolin is traditionally used in ceramics, refractories and as paper coating and filling. But kaolin, as it is demonstrated in this paper, has a bright potential for use in non‐traditional, high value‐added, applications. This is particularly true for its principal component: the mineral species kaolinite which has a chemical structure allowing its functionalization, leading to a variety of potential applications. Kaolinite is a layered 1?:?1 clay mineral, the layer being made of two different sheets, a tetrahedral silica sheet and an octahedral alumina sheet. Large dipole‐dipole interactions, in addition to a network of H‐bonds, link the siloxane surface of a layer to the aluminol surface of another layer, making intercalation of guest species in kaolinite challenging. There is however a limited number of molecular units (molecules or salts) that can directly intercalate in kaolinite to form “pre‐intercalates”. Once intercalated these molecular units can be exchanged by a large number and variety of guests, providing access to the interlayer space of kaolinite, and to its reactive aluminol internal surfaces. The intercalation of molecules of pharmacological interest showed the potential of kaolinite to act as a slow‐releasing agent for drugs, and the intercalation of polymers resulted in the creation of intercalated nanocomposites. The intercalation of ionic liquids gave materials with ionic conductivity properties in the solid‐state. Intercalates are however unstable in water. One needed to make these organo‐inorgano nanohybrid materials resistant to hydrolysis and more thermally stable. The network of aluminol groups on the internal surfaces of kaolinite offers the opportunity to design and create c </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >所有粘土的世界资源非常大。在各种类型的粘土中，2016年高岭土的世界矿山产量为37.0吨，最大的粘土。 Kaolin传统上用于陶瓷，耐火材料和纸涂层和填充物。但是高岭土，正如本文的说明，具有明亮的潜力，用于非传统，高附加值应用。这对于其主要成分尤其如此：矿物物种高岭石具有允许其官能化的化学结构，导致各种潜在的应用。高岭石是一个分层的1？：1粘土矿物，该层由两个不同的片材制成，四面体二氧化硅片和八面体氧化铝片。大偶极偶极相互作用，除了H键的网络之外，将层的硅氧烷表面链接到另一层的铝醇表面，使客舱物种在高岭石具有挑战性中的插入。然而，有有限数量的分子单位（分子或盐），其可直接在高岭石中嵌入以形成“预嵌入”。一旦插入，这些分子单元可以通过大量和各种嘉宾交换，提供对高岭石的层间空间以及其反应性氧化铝内表面的进入。药理学患者分子的插入表明高岭石的潜力作为药物缓慢释放剂，并且聚合物的插层导致嵌入纳米复合材料的产生。离子液体的插层在固态中具有离子电导性能的材料。然而，嵌入在水中是不稳定的。一种需要使这些有机型无机纳米冬次含有耐水解和更热稳定的含量。高岭土内表面上的铝醇组网络提供了设计和创建C的机会 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Detellier Christian&option=202" target="_blank" rel="nofollow">Detellier Christian;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry and Biomolecular SciencesUniversity of OttawaOttawa Ont. K1N6N5 Canada;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kaolinite&option=203" rel="nofollow">Kaolinite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=intercalation&option=203" rel="nofollow">intercalation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanocomposites&option=203" rel="nofollow">nanocomposites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanohybrid materials&option=203" rel="nofollow">nanohybrid materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=grafting&option=203" rel="nofollow">grafting;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sensing&option=203" rel="nofollow">sensing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catalysis&option=203" rel="nofollow">catalysis;</a> </p> <div class="translation"> 机译：高岭石;嵌入;纳米复合材料;纳米混合物;嫁接;感应;催化作用; 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