TiO        <sub >2</sub>2        Nanostructures as Anode Materials for Li/Na‐Ion Batteries

Vazquez‐Santos Maria B.; Tartaj Pedro; Morales Enrique; Amarilla Jose Manuel

摘要

Abstract > Here we summarize some results on the use of TiO <sub>2</sub> nanostructures as anode materials for more efficient Li‐ion (LIBs) and Na‐ion (NIBs) batteries. LIBs are the leader to power portable electronic devices, and represent in the short‐term the most adequate technology to power electrical vehicles, while NIBs hold promise for large storage of energy generated from renewable sources. Specifically, TiO <sub>2</sub> an abundant, low cost, chemically stable and environmentally safe oxide represents in LIBs an alternative to graphite for applications in which safety is mandatory. For NIBs, TiO <sub>2</sub> anodes (or more precisely negative electrodes) work at low voltage, assuring acceptable energy density values. Finally, assembling different TiO <sub>2</sub> polymorphs in the form of nanostructures decreases diffusion distances, increases the number of contacts and offering additional sites for Na + storage, helping to improve power efficiency. More specifically, in this contribution we highlighted our work on TiO <sub>2</sub> anatase mesocrystals of colloidal size. These sophisticate materials; showing excellent textural properties, have remarkable electrochemical performance as anodes for Li/Na‐ion batteries, with conventional alkyl carbonates electrolytes and safe electrolytes based on ionic liquids. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >在这里，我们总结了使用Tio <sub> 2 </ sub>纳米结构的结果作为更高效的锂离子（Libs）和Na离子（NiBs）电池的阳极材料。 LIBS是电力便携式电子设备的领导者，并且在短期最适合的技术中代表电力车辆，而Nibs则保持从可再生源产生的大量能量存储的承诺。具体地，TiO <sub> 2 </ sub>一种丰富，低成本，化学稳定和环保稳定的氧化物，在LIBS中代表了一种用于安全是强制性的应用的替代方法。对于尖端，TiO <sub> 2 </ sub>阳极（或更精确的负电极）在低电压下工作，确保可接受的能量密度值。最后，组装纳米结构形式的不同TiO <sub> 2 </ sub>多晶型物降低扩散距离，增加了触点的数量并为Na + </ sup>存储提供了附加位点，有助于提高功率效率。更具体地说，在这一贡献中，我们突出了我们对胶体尺寸的TiO <sub> 2 </ sub>锐钛矿晶体的作品。这些精致的材料;显示出优异的纹理性质，具有显着的电化学性能作为Li / Na离子电池的阳极，具有常规碳酸烷基酯电解质和基于离子液体的安全电解质。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共14页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Vazquez‐Santos Maria B.&option=202" target="_blank" rel="nofollow">Vazquez‐Santos Maria B.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tartaj Pedro&option=202" target="_blank" rel="nofollow">Tartaj Pedro;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Morales Enrique&option=202" target="_blank" rel="nofollow">Morales Enrique;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Amarilla Jose Manuel&option=202" target="_blank" rel="nofollow">Amarilla Jose Manuel;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Instituto de Ciencia de Materiales de Madrid CSICCampus Universitario de Cantoblanco28049 Madrid Spain;</p> <p>Instituto de Ciencia de Materiales de Madrid CSICCampus Universitario de Cantoblanco28049 Madrid Spain;</p> <p>Instituto de Ciencia y Tecnología de Polímeros CSICC/Juan de la Cierva 3 28006 Madrid Spain;</p> <p>Instituto de Ciencia de Materiales de Madrid CSICCampus Universitario de Cantoblanco28049 Madrid Spain;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mesocrystals&option=203" rel="nofollow">Mesocrystals;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=renewable energy&option=203" rel="nofollow">renewable energy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=TiO 2 nanostructures&option=203" rel="nofollow">TiO 2 nanostructures;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ionic liquids&option=203" rel="nofollow">ionic liquids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=safety&option=203" rel="nofollow">safety;</a> </p> <div class="translation"> 机译：中胚层;可再生能量;TiO 2纳米结构;离子液体;安全; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704018599110.html">Carbon-decorated Li_4Ti_5O_(12)/rutile TiO_2 mesoporous microspheres with nanostructures as high-performance anode materials in lithium-ion batteries</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lin Gao&option=202" 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carbon-doped TiO2 bronze nanostructures as anode materials for high performance lithium batteries</a> <b>[P]</b> . <span> 外国专利：  JP2018535177A </span> <span> . 2018-11-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：直接合成碳掺杂的TiO2青铜纳米结构作为高性能锂电池的负极材料 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130407210413.html">DIRECT SYNTHESIS OF CARBON DOPED TiO2-BRONZE NANOSTRUCTURES AS ANODE MATERIALS FOR HIGH PERFORMANCE LITHIUM BATTERIES</a> <b>[P]</b> . <span> 外国专利：  US2018261838A1 </span> <span> . 2018-09-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：直接合成碳掺杂的TiO2-青铜纳米结构作为高性能锂电池的阳极材料 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: 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TiO 22 Nanostructures as Anode Materials for Li/Na‐Ion Batteries

摘要

TiO ₂2 Nanostructures as Anode Materials for Li/Na‐Ion Batteries