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High-frequency asymptote for the velocity auto-correlation function spectrum of argon-like systems

机译:类氩气系统速度自相关函数谱的高频渐近线

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摘要

The work is devoted to the analysis of high-frequency behavior of the velocity auto-correlation function spectrum VCombining right arrow above(ω) for argon-like systems. The theoretical predictions are compared with results of computer simulations of VCombining right arrow above(ω). It is shown that (1) VCombining right arrow above(ω) takes the exponential behavior VCombining right arrow above(ω)ωq(n)ω→exp(- (ωτ _a(n))p(n)), where p(n), q(n), and τ _a(n) are the definite functions of the steepness exponent n for the power repulsive part of interparticle potential; (2) there is full agreement between theoretical predictions and the values of p(n), q(n), and τ _a(n) obtained in computer simulations. Weighty arguments about the universal character of the exponential frequency decay exp(-(ωτ _a(n)) p(n)) for spectra of different correlation functions are given. The experimental spectrum of the depolarized light scattering in argon for high frequencies is analyzed. It is shown that the steepness exponent n for the power repulsive potential takes the value: n ≈ 24 that is essentially different from n = 12 characteristic for the Lennard-Jones potential.
机译:这项工作致力于分析类似氩气系统的速度自相关函数谱VCombining上面的右箭头(ω)的高频行为。将理论预测结果与VCombining上方的右箭头(ω)的计算机仿真结果进行比较。结果表明:(1)上方(ω)的VCombining右箭头采取指数行为上方(ω)ωq(n)ω→exp(-(ωτ_a(n))p(n))的VCombining右箭头n),q(n)和τ_a(n)是粒子间电势的功率排斥部分的陡峭指数n的确定函数; (2)理论预测与在计算机模拟中获得的p(n),q(n)和τ_a(n)的值完全一致。给出了有关不同相关函数谱的指数频率衰减exp(-(ωτ_a(n))p(n))的通用性的权重参数。分析了高频下氩气中去偏振光散射的实验光谱。结果表明,功率排斥势的陡峭指数n取值:n≈24,与Lennard-Jones势的n = 12特征基本不同。

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