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首页> 外文期刊>The Journal of Chemical Physics >Exciton dynamics in chromophore aggregates with correlated environment fluctuations
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Exciton dynamics in chromophore aggregates with correlated environment fluctuations

机译:具有相关环境波动的发色团聚集体的激子动力学

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摘要

We study the effects of correlated molecular transition energy fluctuations in molecular aggregates on the density matrix dynamics, and their signatures in the optical response. Correlated fluctuations do not affect single-exciton dynamics and can be described as a nonlocal contribution to the spectral broadening, which appears as a multiplicative factor in the time-domain response function. Intraband coherences are damped only by uncorrelated transition energy fluctuations. The signal can then be expressed as a spectral convolution of a local contribution of the uncorrelated fluctuations and the nonlocal contribution of the correlated fluctuations.
机译:我们研究了分子聚集体中相关的分子跃迁能波动对密度矩阵动力学的影响,以及它们在光学响应中的特征。相关的涨落不影响单激子动力学,可以描述为对光谱展宽的非局部贡献,它在时域响应函数中表现为倍增因子。带内相干仅被不相关的过渡能量波动所衰减。然后可以将该信号表示为不相关波动的局部贡献和相关波动的非局部贡献的频谱卷积。

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