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Theory of aging in structural glasses

机译:结构玻璃的老化理论

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摘要

The random first-order transition theory of the dynamics of supercooled liquids is extended to treat aging phenomena in nonequilibrium structural glasses.A reformulation of the idea of "entropic droplets" in terms of libraries of local energy landscapes is introduced which treats in a uniform way the supercooled liquid (reproducing earlier results) and glassy regimes.The resulting microscopic theory of aging makes contact with the Nayaranaswamy-Moynihan-Tool nonlinear relaxation formalism and the Hodge-Scherer extrapolation of the Adam-Gibbs formula,but deviations from both approaches are predicted and shown to be consistent with experiment.The nonlinearity of glassy relaxation is shown to quantitatively correlate with liquid fragility.The residual non-Arrhenius temperature dependence of relaxation observed in quenched glasses is explained.The broadening of relaxation spectra in the nonequilibrium glass with decreasing temperature is quantitatively predicted.The theory leads to the prediction of spatially fluctuating fictive temperatures in the long-aged glassy state,which have non-Gaussian statistics.This can give rise to "ultraslow" relaxations in systems after deep quenches.
机译:扩展了过冷液体动力学的随机一阶跃迁理论,以处理非平衡结构玻璃中的老化现象。引入了“熵液滴”的概念,即根据局部能态图谱重新定义了统一的处理方式老化的微观理论与Nayaranaswamy-Moynihan-Tool非线性松弛形式主义和Adam-Gibbs公式的Hodge-Scherer外推法相联系,但可以预测这两种方法的偏差玻璃弛豫的非线性与液体的脆性有定量关系。解释了在淬火玻璃中观察到的弛豫的残余非阿伦尼乌斯温度依赖性。随着温度的降低,非平衡玻璃的弛豫谱变宽。是定量预测的。具有非高斯统计的长时玻璃态的空间波动虚构温度的方向。这可能导致深淬后系统中的“超低速”弛豫。

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