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If C-H Bonds Could Talk: Selective C-H Bond Oxidation

机译:如果C-H键可以说:选择性C-H键氧化

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摘要

C-H oxidation has a long history and an ongoing presence in research at the forefront of chemistry and interrelated fields. As such, numerous highly useful articles and reviews have been written on this subject. Logically, these are generally written from the perspective of the scope and limitations of the reagents employed. This Minireview instead attempts to emphasize chemoselectivity imposed by the nature of the substrate. Consequently, many landmark discoveries in the field of C-H oxidation are not discussed, but hopefully the perspective taken herein will allow C-H oxidation reactions to be more readily incorporated into synthetic planning.
机译:C-H氧化历史悠久,在化学和相关领域的最前沿一直处于研究中。这样,关于该主题已经写了许多非常有用的文章和评论。从逻辑上讲,这些通常是从所用试剂的范围和限制的角度来写的。相反,该Miniview试图强调由底物性质引起的化学选择性。因此,没有讨论C-H氧化领域中的许多重大发现,但是希望本文所采用的观点将允许C-H氧化反应更容易地纳入合成计划中。

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