INTERACTIONS IN CRYSTALS .73. THE STRUCTURES OF 1,2,4,5-TETRAKIS(TRIMETHYLSILYL)BENZENE AND OF ITS SOLVENT-SEPARATED RADICAL ANION SALT [NA-CIRCLE-PLUS(H3COCH2CH2OCH3)(3)] [((H3C)(3)SI)(4)H2C6-CENTER-DOT-CIRCLE-MINUS]

Bock H.; Nagel N.; Havlas Z.; Ansari M.

首页> 外文期刊>Journal of Organometallic Chemistry >INTERACTIONS IN CRYSTALS .73. THE STRUCTURES OF 1,2,4,5-TETRAKIS(TRIMETHYLSILYL)BENZENE AND OF ITS SOLVENT-SEPARATED RADICAL ANION SALT [NA-CIRCLE-PLUS(H3COCH2CH2OCH3)(3)] [((H3C)(3)SI)(4)H2C6-CENTER-DOT-CIRCLE-MINUS]

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INTERACTIONS IN CRYSTALS .73. THE STRUCTURES OF 1,2,4,5-TETRAKIS(TRIMETHYLSILYL)BENZENE AND OF ITS SOLVENT-SEPARATED RADICAL ANION SALT [NA-CIRCLE-PLUS(H3COCH2CH2OCH3)(3)] [((H3C)(3)SI)(4)H2C6-CENTER-DOT-CIRCLE-MINUS]

机译：晶体中的相互作用.73。 1,2,4,5-四（三甲基甲硅烷基）苯及其溶剂分离的自由基阴离子盐[NA-CIRCLE-PLUS（H3COCH2CH2OCH3）（3）] [（（H3C）（3）SI）（4）的结构）H2C6-CENTER-DOT-CIRCLE-MINUS]

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Reduction of 1,2,4,5-tetrakis(trimethylsilyl)benzene at a sodium-metal mirror under aprotic conditions and an argon atmosphere yields red needles of its solvent-separated radical anion salt. The structure, determined in a 150 K cold N-2 flow, is discussed in comparison with that of the neutral starting molecule, literature examples and results of MNDO calculations. [References: 35]

机译：在质子惰性条件和氩气氛下，在钠金属镜上还原1,2,4,5-四（三甲基甲硅烷基）苯，会产生红色针状溶剂分离的自由基阴离子盐。在150 K冷N-2流中确定的结构，与中性起始分子的结构，文献实例和MNDO计算结果进行了比较。 [参考：35]

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《Journal of Organometallic Chemistry》 |1995年第2期|共9页
作者
Bock H.; Nagel N.; Havlas Z.; Ansari M.;
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正文语种 eng
中图分类有机化学;
关键词
Silicon; Interactions in crystals; Radical anion salt; Mndo calculations; 1; 2; 4; 5-tetrakis(trimethylsilyl)benzene; Single electron reduction; Organosilicon compounds; Photoelectron-spectrum; Molecular-properties; Benzene dianion; Chemistry; Systems;

机译：硅;晶体中的相互作用;自由基阴离子盐;Mndo计算;1;2;4;5-四（三甲基甲硅烷基）苯;单电子还原;有机硅化合物;光电子光谱;分子性质;苯二阴离子;化学;体系;

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1. INTERACTIONS IN CRYSTALS .73. THE STRUCTURES OF 1,2,4,5-TETRAKIS(TRIMETHYLSILYL)BENZENE AND OF ITS SOLVENT-SEPARATED RADICAL ANION SALT [NA-CIRCLE-PLUS(H3COCH2CH2OCH3)(3)] [((H3C)(3)SI)(4)H2C6-CENTER-DOT-CIRCLE-MINUS] [J] . Bock H., Nagel N., Havlas Z., Journal of Organometallic Chemistry . 1995,第1a2期

机译：晶体中的相互作用.73。 1,2,4,5-四（三甲基甲硅烷基）苯及其溶剂分离的自由基阴离子盐[NA-CIRCLE-PLUS（H3COCH2CH2OCH3）（3）] [（（H3C）（3）SI）（4）的结构）H2C6-CENTER-DOT-CIRCLE-MINUS]
2. Synthesis and structure of the silylated benzene radical anion salts [K([18]crown-6){C_6H_4(SiMe_3)_2-1,4}] and [K([18]crown-6)(THF)_2][C_6H_2(SiMe _3)_4-1,2,4,5] [J] . Hitchcock P.B., Lappert M.F., Protchenko A.V. Journal of Organometallic Chemistry . 2011,第10期

机译：甲硅烷基化苯自由基阴离子盐[K（[18] crown-6）{C_6H_4（SiMe_3）_2-1,4}]和[K（[18] crown-6）（THF）_2] [C_6H_2 （SiMe _3）_4-1,2,4,5]
3. INTERACTIONS IN CRYSTALS .78. THE STRUCTURE OF NAKED 9,10-BIS(TRIMETHYLSILYL)ANTHRACENE RADICAL ANION [J] . Bock H., Nagel N., Claridge RFC., Journal of Organometallic Chemistry . 1995,第1a2期

机译：晶体相互作用.78。裸9,10-双（三甲基甲硅烷基）对蒽自由基阴离子的结构
4. Hydrothermal Synthesis and Crystal Structure of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: Co(Him)2(μ4-bta)l/2n (Him=imidazole) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸酯为桥联配体的水热合成和晶体结构：Co（Him）2（μ4-bta）l / 2 n（Him =咪唑）
5. EPR STUDIES: I. GAMMA-IRRADIATED SUCCINIC ACID SINGLE-CRYSTALS. II. FLUORINATED BENZENE ANION RADICALS. III. FLUORINATED CYCLOHEXADIENYL RADICALS. [D] . YIM, MOON BIN. 1974

机译：EPR研究：I.γ射线辐照的蔗糖酸单晶。二。氟化苯阴离子自由基。三，氟化环己二烯基自由基。
6. Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations [O] . Xiaoyu Chen, Feng Gao, Wuqin Yang -1

机译：四（烷硫基）苯自由基阳离子导电π-堆叠二聚体的单晶X射线结构
7. CCDC 1050062: Experimental Crystal Structure Determination : catena-[bis(dimethylammonium) octakis(mu-hydroxo)-tris(mu-1,2,4,5-tetrakis[(4-carboxylato)phenoxymethyl]benzene)-hexaaqua-hexa-yttrium unknown solvate monohydrate] [O] . Luebke, Ryan, Belmabkhout, Youssef, Weseliński, Łukasz J., 2015

机译：CCDC 1050062：实验晶体结构测定：连环-[双（二甲基铵）八（μ-羟基）-三（μ-1,2,4,5-四[[4-羧基）苯氧基甲基]苯）-六水-六-钇未知一水合溶剂化物]

INTERACTIONS IN CRYSTALS .73. THE STRUCTURES OF 1,2,4,5-TETRAKIS(TRIMETHYLSILYL)BENZENE AND OF ITS SOLVENT-SEPARATED RADICAL ANION SALT [NA-CIRCLE-PLUS(H3COCH2CH2OCH3)(3)] [((H3C)(3)SI)(4)H2C6-CENTER-DOT-CIRCLE-MINUS]

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