Asymmetric nucleophilic #alpha#-amino-acylation with metalated chiral amino niriles:enantio-selective synthesis of 3-substituted 5-amino-4-oxo-esters via asymmetric Michael addition

Enders Dieter; Shilvock John P.

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Asymmetric nucleophilic #alpha#-amino-acylation with metalated chiral amino niriles:enantio-selective synthesis of 3-substituted 5-amino-4-oxo-esters via asymmetric Michael addition

机译：金属手性氨基腈的不对称亲核＃alpha＃-氨基酰化：通过不对称迈克尔加成反应的对映体选择性合成3-取代的5-氨基-4-氧代酯

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来源
《Journal of the Chemical Society. Dalton Transactions》 |1999年第12期|共4页
作者
Enders Dieter; Shilvock John P.;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
alpha; -amino-acylation; chiral amino nitriles; 3-substituted 5-amino-4-oxo-esters; Michael addition;

机译：α;-氨基酰化;手性氨基腈;3-取代的5-氨基-4-氧代酯;迈克尔加成;

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1. Asymmetric nucleophilic #alpha#-amino-acylation with metalated chiral amino niriles:enantio-selective synthesis of 3-substituted 5-amino-4-oxo-esters via asymmetric Michael addition [J] . Enders Dieter, Shilvock John P. Journal of the Chemical Society. Dalton Transactions . 1999,第12期

机译：金属手性氨基腈的不对称亲核＃alpha＃-氨基酰化：通过不对称迈克尔加成反应的对映体选择性合成3-取代的5-氨基-4-氧代酯
2. Asymmetric synthesis of 3-substituted indole derivatives containing tetrahydrothiophene via cascade sulfa-Michael/Michael additions catalyzed by a chiral squaramide catalyst [J] . Li Ying-He, Zhao Bo-Liang, Gao Yu, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2014,第23期

机译：手性方酰胺催化剂催化级联磺胺-迈克尔/迈克尔加成反应不对称合成含四氢噻吩的3-取代吲哚衍生物
3. Michael addition reactions between various nucleophilic glycine equivalents and (S,E)-1-enoyl-5-oxo-N-phenylpyrrolidine-2-carboxamide, an optimal type of chiral Michael acceptor in the asymmetric synthesis of beta-phenyl pyroglutamic acid and related compounds [J] . Ellis TK, Ueki H, Tiwari R, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2009,第22期

机译：各种亲核甘氨酸当量与（S，E）-1-烯丙基-5-氧代-N-苯基吡咯烷-2-羧酰胺之间的迈克尔加成反应（β-苯基焦谷氨酸不对称合成中的最佳手性迈克尔受体类型）化合物
4. Michael Addition Reactions between Nucleophilic GlycineEquivalents and Acrylic Acid Derivatives as a Practicaland Generalized Approach to the Asymmetric Synthesisof II-Substituted-a-Amino Acids [C] . Vadim A. Soloshonok, Hisanori Ueki, Trevor K. Ellis ACS symposium asymmetric synthesis and application of α-amino acids . 2009

机译：亲核糖糖糖尿剂与丙烯酸衍生物之间的迈克尔添加反应作为不对称合成的不对称 - A-氨基酸的不对称方法的普遍化方法
5. Asymmetric synthesis of C-1 substituted cocaine analogues using sulfinimine (N-sulfinyl imine) chemistry and vinylaluminum addition to sulfinimines (n-sulfinyl imines) for the asymmetric synthesis of alpha-substituted-beta-amino esters. [D] . Gaddiraju, Narendra Varma. 2013

机译：不对称合成C-1取代可卡因类似物，使用亚磺胺（N-亚磺酰基亚胺）化学物质和乙烯基铝加成亚磺胺（n-亚磺酰基亚胺）进行α-取代-β-氨基酯的不对称合成。
6. Synthesis of chiral 3-substituted 3-amino-2-oxindoles through enantioselective catalytic nucleophilic additions to isatin imines [O] . Hélène Pellissier 2018

机译：通过对映异构亚胺的对映选择性催化亲核加成反应合成手性3-取代的3-氨基-2-氧吲哚
7. Asymmetric synthesis of beta-amino acids via the Michael addition of chiral metal amides [O] . Davies, SG, Ichihara, O 1997

机译：通过手性金属酰胺的迈克尔加成反应不对称合成β-氨基酸

Asymmetric nucleophilic #alpha#-amino-acylation with metalated chiral amino niriles:enantio-selective synthesis of 3-substituted 5-amino-4-oxo-esters via asymmetric Michael addition

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