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Anodic oxidation of benzyl alcohol with and without redox mediators using modified electrodes

机译:使用修饰电极在有和没有氧化还原介体的情况下对苯甲醇进行阳极氧化

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Benzyl alcohol was anodically oxidized with and without redox mediators using modified electrodes. The morphologies and characteristics of the modified electrodes with and without redox mediators were analyzed. Cyclic voltammograms; of the modified electrodes showed that the capacitive current and area of the solution-electrode interface were rather large. The CV redox peak with fixed hydroquinone was larger than that without fixed hydroquinone. The yield of benzaldehyde obtained by using the modified anode containing immobilized hydroquinone was better/worse than that obtained with a Pt anode without/with hydroquinone in solution, respectively. [References: 14]
机译:使用修饰的电极,在有和没有氧化还原介体的情况下,对苯甲醇进行阳极氧化。分析了带有和不带有氧化还原介体的修饰电极的形貌和特性。循环伏安图修改后的电极的结果表明,电容电流和溶液-电极界面的面积都很大。固定氢醌的CV氧化还原峰比不固定氢醌的CV氧化还原峰大。通过使用含有固定的氢醌的改性阳极获得的苯甲醛的产率分别比使用在溶液中没有/有氢醌的铂阳极获得的苯甲醛的更好/更差。 [参考:14]

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