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Fe-Pb-Sb (Iron-Lead-Antimony)

机译:Fe-Pb-Sb(铁铅锑)

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摘要

The previous review of this system by [1992Rag] presented a tentative isothermal section at 1200 deg C, depicting the liquid miscibility gap in the ternary region. Recently, [2004Sun] reported an isothermal section at 227 deg C (500 K), where no ternary compounds were found.Binary SystemsIn the Fe-Pb system, there is very little mutual solubility between Fe and Pb in the liquid or solid state. There are two intermediate phases in the Fe-Sb system. The e phase, with a NiAs-type hexagonal structure has a maximum homogeneity range of 40-47 at.percent Sb [1993Oka]. FeSb_2 is a line compound with orthorhombic symmetry. The Pb-Sb phase diagram [Massalski2] is a simple eutectic type, with the eutectic composition and temperature at 17.5 at.percent Sb and 251.7 deg C, respectively. The maximum solubilities of Sb in Pb and of Pb in Sb are 5.8 and 1.9 at.percent, respectively.
机译:[1992Rag]对该系统的先前评论提出了一个在1200℃下的试验性等温截面,描绘了三元区域中的液体混溶间隙。最近,[2004Sun]报告了在227摄氏度(500 K)下的等温截面,未发现三元化合物。二元体系在Fe-Pb体系中,Fe和Pb在液态或固态之间的互溶性很小。 Fe-Sb系统中有两个中间相。具有NiAs型六边形结构的e相的最大均匀度范围为Sb的40-47 at。%[1993Oka]。 FeSb_2是具有正交对称性的线化合物。 Pb-Sb相图[Massalski2]是一种简单的共晶类型,其共晶成分和温度分别为17.5 at。%Sb和251.7℃。 Pb中Sb的最大溶解度和Sb中Pb的最大溶解度分别为5.8和1.9 at。%。

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