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Rohm and Haas patents pigmented polymer

机译:罗门哈斯(Rohm and Haas)专利颜料聚合物

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Rohm and Haas has received a patent for a polymer composition comprised of organic colorant particles; and polymer particles comprised of polymerized units of phosphorus acid monomer and having first phosphorus acid groups, wherein: i) the polymer particles are prepared by aqueous emulsion polymerization of the phosphorus acid monomer at a pH of less than 2, or ii) the polymer composition is comprised of a level of water soluble polymer having second phosphorus acid groups defined by ratios of equivalents of second phosphorus acid groups to equivalents of first phosphorus acid groups in the range of less than or equal to 1.5, wherein each of the polymer particles are multistage polymer particles comprised of a) a first polymer comprised of a polymerized unit of a multiethylenically unsaturated monomer, polymerized units of the phosphorus acid monomer, and the first phosphorus acid groups, wherein the first polymer has a glass transition temperature in the range of from -60° C to 35° C; and b) a second polymer having a glass transition temperature in the range of from -60° C to 35~(deg) C, wherein a weight percent of the first " phosphorus acid groups in the second polymer, based on a weight of the second polymer, is 10% weight or less of a, weight percent of the first phosphorus acid groups in the first polymer, based on a weight of the first polymer and wherein the average weight ratio of the first polymer to the second polymer is in the range of from 1:2 to 1:20.
机译:罗门哈斯(Rohm and Haas)已获得由有机着色剂颗粒组成的聚合物组合物的专利;以及由含磷酸单体的聚合单元组成并具有第一磷酸基团的聚合物颗粒,其中:i)所述聚合物颗粒是通过在小于2的pH下将所述磷酸单体进行水乳液聚合制备的;或ii)所述聚合物组合物包含具有第二磷酸基团的水溶性聚合物的水平,该第二磷酸基团由第二磷酸基团的当量与第一磷酸基团的当量之比限定在小于或等于1.5的范围内,其中每个聚合物颗粒是多级的聚合物颗粒,包括:a)由多烯键式不饱和单体的聚合单元,磷酸单体的聚合单元和第一磷酸基团组成的第一聚合物,其中第一聚合物的玻璃化转变温度为- 60°C至35°C; b)玻璃化转变温度为-60℃至35℃的第二聚合物,其中第二聚合物中第一“磷酸基团”的重量百分比基于所述聚合物的重量计。相对于第一聚合物的重量,第二聚合物为第一聚合物中第一磷酸基团重量的10%重量或更少,并且其中第一聚合物与第二聚合物的平均重量比为范围从1:2到1:20。

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