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Towards a complete recycling of phosphorus in wastewater treatment - options in Germany

机译:在废水处理中实现磷的完全回收-德国的选择

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摘要

Global reserves of mineral phosphorus are finite and the recycling of phosphorus from wastewater, a significant sink for phosphorus, can contribute to a more sustainable use. In Germany, Switzerland, and the Netherlands, an increasing percentage of municipal sewage sludge is incinerated and the contained phosphorus is lost. This paper reviews current technologies and shows that a complete phosphorus recovery from wastewater is technically feasible. Depending on the composition of the sewage sludge ash (SSA), there are various options for phosphorus recovery that are presented. Iron-poor SSAs can be used directly as substitute for phosphate rock in the electrothermal phosphorus process. SSAs with low heavy metal contents can be used as fertilizer without prior metal elimination. Ashes not suitable for direct recycling can be processed by thermal processes. Operators of wastewater treatment plants can additionally influence the ash composition via the selection of precipitants and the control of (indirect) dischargers. This way, they can choose the most suitable phosphorus recovery option. For sewage sludge that is co-incinerated in power plants, municipal waste incinerators or cement kilns phosphorus recovery is not possible. The phosphorus is lost forever.
机译:全球矿物质磷的储量是有限的,废水中的磷回收是磷的重要汇,可以促进更可持续的利用。在德国,瑞士和荷兰,城市污水污泥的焚化比例不断提高,所含磷也流失了。本文回顾了当前的技术,并表明从废水中完全回收磷在技术上是可行的。根据污水污泥灰(SSA)的组成,提出了多种回收磷的选择。贫铁SSA可在电热磷工艺中直接用作磷矿石的替代品。重金属含量低的SSA可用作肥料,而无需事先消除金属。不适合直接回收的灰可以通过热处理来处理。废水处理厂的运营商还可以通过选择沉淀剂和控制(间接)排放装置来影响灰分的组成。这样,他们可以选择最合适的磷回收选项。对于在电厂中共同焚化的污水污泥,市政废物焚化炉或水泥窑无法进行磷回收。磷永远消失了。

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