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首页> 外文期刊>The Journal of Chemical Physics >Relaxation in random pores
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Relaxation in random pores

机译:松弛毛孔

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To study the dynamics of a binary liquid mixture in glass pores we have performed a molecular dynamics simulation and measured the concentration fluctuation autocorrelation function F-m(q,t) and several other dynamic functions. The relaxation pattern of F-m may be described with an exponentially decaying diffusion term and a logarithmically decaying activation term. Although the system is at a very high temperature in the one-phase region, the results for the velocity autocorrelation functions and the mean-square displacement functions are deceptively similar to those of the bulk when the bulk is in its two-phase region. We discuss what this may mean when the pore size is very large. (C) 1998 American Institute of Physics. [References: 14]
机译:为了研究玻璃孔中二元液体混合物的动力学,我们进行了分子动力学模拟,并测量了浓度波动自相关函数F-m(q,t)和其他几个动力学函数。 F-m的弛豫模式可以用指数衰减的扩散项和对数衰减的激活项来描述。尽管系统在单相区域处于很高的温度下,但是当块体处于其两相区域时,速度自相关函数和均方位移函数的结果在外观上与块体的相似。我们讨论了当孔径很大时这可能意味着什么。 (C)1998美国物理研究所。 [参考:14]

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