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Mechanical Properties and Flame Retardancy of SEBS-based Composites Filled with Magnesium Hydroxide

机译:填充氢氧化镁的SEBS基复合材料的力学性能和阻燃性

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摘要

The flame-retardancy and mechanical properties of styrene-ethylene/butylene-styrene block copolymer(SEBS)based composites,containing SEBS blended with a paraffinic hydrocarbon extender oil,copolymer polypropylene(PP),and magnesium hydroxide(MH)or silane coupling agent surface-treated magnesium hydroxide(m-MH)were investigated.A maleic anhydride-grafted SEBS(MA-SEBS)was used as a polymer modifier for some composites.As the amount of MH or m-MH increased,the flame-retardancy of composites improved,while the tensile strength and elongation at break decreased,and the melt property of the composites became worse as well.When the oil-filled SEBS(O-SEBS)was partially replaced by MA-SEBS,the tensile strength of the composites increased,and elongation at break decreased.Furthermore replacing O-SEBS with MA-SEBS and treating MH with silane coupling agent(simultaneously)improved the tensile strength of the composites by a large margin.The phase structure of the composites was characterised using scanning electron microscopy(SEM)and this revealed that the particle-matrix interfacial bonding was improved through the addition of MA-SEBS.The stability of the composites was investigated by thermogravimetric analysis(TGA).
机译:苯乙烯-乙烯/丁烯-苯乙烯嵌段共聚物(SEBS)基复合材料的阻燃性和力学性能,含SEBS和链烷烃增量油,共聚物聚丙烯(PP)和氢氧化镁(MH)或硅烷偶联剂表面研究了处理后的氢氧化镁(m-MH)。马来酸酐接枝的SEBS(MA-SEBS)被用作某些复合材料的聚合物改性剂。随着MH或m-MH含量的增加,复合材料的阻燃性复合材料的抗拉强度和断裂伸长率降低,并且熔体性能也变差。当用MA-SEBS代替油性SEBS(O-SEBS)时,复合材料的抗拉强度提高此外,用MA-SEBS代替O-SEBS,再用硅烷偶联剂处理MH,同时大幅度提高了复合材料的拉伸强度。扫描电镜(SEM)分析表明,通过加入MA-SEBS可以改善颗粒-基体的界面结合。通过热重分析(TGA)研究了复合材料的稳定性。

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