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The microwave-assisted photo-catalytic degradation of organic dyes

机译:微波辅助光催化降解有机染料

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摘要

In this study, TiO2 photo-catalyst balls produced by the chemical vapour deposition method werenused for degradation of organic dyes in which simultaneous irradiation of microwave and UV wasnevaluated. An electrodeless UV lamp that emits UV upon the irradiation of microwave wasndeveloped to irradiate microwave and UV simultaneously. The degradation reaction rate wasnshown to be higher with higher microwave intensity, under stronger acidic or basic conditions,nand with a larger amount of O2 gas or H2O2 addition. The effect of addition of H2O2 was notnsignificant when photo-catalysis was used without additional microwave irradiation or whennmicrowave was irradiated without the use of photo-catalysts. When H2O2 was added undernsimultaneous use of photo-catalysis and microwave irradiation, however, considerably higherndegradation reaction rates were observed.
机译:在这项研究中,通过化学气相沉积法制备的TiO2光催化剂球被用于降解有机染料,同时评估了微波和紫外线的同时照射。为了在同时照射微波和紫外线的同时,开发了一种在照射微波的同时发出紫外线的无电极紫外线灯。微波强度越高,在酸性或碱性条件下,以及添加的氧气量或过氧化氢量越大,降解反应速率越高。当在不进行额外的微波辐射的情况下使用光催化或在不使用光催化剂的情况下进行微波辐射时,添加H2O2的影响并不显着。但是,在同时使用光催化和微波辐射的情况下添加H2O2时,观察到更高的降解反应速率。

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