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Chemiluminescene of aqueous solutions of sodium and magnesium peroxydisulfates in the presence of aliphatic alcohols and dimethyl sulfoxide

机译:脂肪醇和二甲基亚砜存在下过氧二硫酸钠和过氧化二镁水溶液的化学发光

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摘要

The phenomenon of the chemiluminescence in the aqueous solutions of the peroxydisulfates in the presence of metal magnesium is studied. It is assertained, that a phenomenn of chemiluminescence has a free-radical nature. The injection of the organic disolvents (aliphatic alcoohols and dimethyl sulfoxide) in the solution leads to the increase of the radiation intensity. This effect is connected with their partisipation in the reaction of peroxydisulfates decomposition.
机译:研究了在金属镁存在下过氧二硫酸盐水溶液中化学发光现象。可以确定的是,化学发光现象具有自由基性质。在溶液中注入有机溶剂(脂肪醇和二甲基亚砜)导致辐射强度增加。这种作用与其在过氧化二硫酸盐分解反应中的参与有关。

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