Physical-chemical fenomena on phase boundary vinyl monomer-water solution of polyvinylpyrrolidone

摘要

The results of investigation of physical-chemical process, that occur on phase boundary hydrofobic vinyl monomer-water solution of polyvinylpyrrolidone (PVP) in context of their influence on polymerization kinetics in these systems are adduced. The exact comformity between relaxation time of PVP macromolecules on interfacial surface, value of interfacial interaction and kinetic parameters of polymerization is determined.