Unidirectional Growth of Microbumps on (111)-Oriented and Nanotwinned Copper

摘要

Highly oriented [111] Cu grains with densely packed nanotwins have been fabricated by direct-current electroplating with a high stirring rate. The [lll]-oriented and nanotwinned Cu (nt-Cu) allow for the unidirectional growth of Cu_6Sn_5 intermetallics in the microbumps of three-dimensional integrated-circuit packaging; a uniform microstructure in a large number of microbumps of controlled orientation can be obtained. The high-density twin boundaries in the nt-Cu serve as vacancy sinks during the solid-state reaction between Pb-free solder and Cu and greatly reduce the formation of Kirkendall (or Frenkel) voids.