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A hands-on approach to teaching environmental awareness and pollutant remediation to undergraduate chemistry students

机译:向本科化学专业学生教授环境意识和污染物修复的实践方法

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Background: One of the unfortunate side effects of the industrial revolution has been the constant assault of the environment with various forms of pollution. Lately, this issue has taken a more critical dimension as prospects of global climate change and irreversible ecosystem damage are becoming a reality. Purpose: College graduates (especially chemists), should therefore not only be aware of these issues but also be taught how chemistry can help reduce environmental pollution. Furthermore, the role and importance of chemistry in sustainable development and solving environmental problems needs to be highlighted. Programme/intervention description: To this effect, we have designed a simple undergraduate experiment that is based on the green chemistry approach of using photolytic oxidation to degrade a model organic pollutant. This approach used UV light and hydrogen peroxide to produce reactive hydroxyl radicals, which subsequently break down and degrade Acridine Orange (model pollutant). The dye degradation was monitored spectrophotometrically and the apparent rate of decolouration was found to be first order. Possible radical initiated mechanisms that may be involved in this remediation experiment have been used to explain the observed dye decolouration. Sample: To test the usefulness of this newly developed experiment, we incorporated it as a module into a second year 'Professional skills' chemistry course with an enrollment of six female students. Anonymous survey of the students after the completion of the module was very positive and indicated that objectives of the experiment were satisfactorily achieved. Results: We believe this experiment not only raises students' awareness about green chemistry and environmental issues, but also teaches them valuable experimental skills such as experimental design, data manipulation and basic kinetics. Survey of students who were taught this unit in a second year course was very positive and supported the usefulness of this unit for chemistry students. Conclusions: In summary, we describe here an undergraduate chemistry experiments that was found to be very effective in teaching students about the hazards of environmental pollution and the role of green chemistry in solving *real-life' problems, as well as chemical kinetics, data acquisition and manipulation.
机译:背景:工业革命的不幸副作用之一是不断遭受各种形式污染的环境的袭击。最近,随着全球气候变化和不可逆转的生态系统破坏的前景成为现实,这个问题已成为一个更为关键的方面。目的:因此,大学毕业生(尤其是化学家)不仅应该意识到这些问题,还应该学习化学如何帮助减少环境污染。此外,需要强调化学在可持续发展和解决环境问题中的作用和重要性。程序/干预说明:为此,我们设计了一个简单的大学实验,该实验基于绿色化学方法,该方法使用光解氧化降解模型有机污染物。这种方法使用紫外线和过氧化氢产生反应性羟基,随后分解并降解A啶橙(模型污染物)。用分光光度法监测染料的降解,发现表观脱色速率为一级。修复实验中可能涉及的可能的自由基引发机理已用于解释观察到的染料脱色。样本:为了测试这项新开发实验的有效性,我们将其作为模块纳入了第二年的“专业技能”化学课程中,招收了六名女学生。完成该模块后,对学生的匿名调查非常积极,表明该实验的目标已令人满意地实现。结果:我们相信该实验不仅可以提高学生对绿色化学和环境问题的认识,还可以教给他们宝贵的实验技能,例如实验设计,数据处理和基本动力学。对在第二年课程中学习过该单元的学生的调查非常积极,并支持该单元对化学专业学生的有用性。结论:总而言之,我们在此描述了一个本科化学实验,该实验被发现对于教给学生有关环境污染的危害和绿色化学在解决*现实生活中的问题以及化学动力学,数据方面的作用非常有效。采集和操纵。

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