Electrochemical noise measurements of stainless steel in high temperature water

摘要

Corrosion in a high purity aqueous environment simulating a boiling water reactor (BWR) is addressed in this work. This condition necessitates autoclave experiments under high pressure and temperature. Long-term electrochemical noise measurements were explored as a mean to detect and monitor stress corrosion cracking phenomenon. An experimental set up, designed to insulate the working electrode from external interference, made possible to detect and monitor stress corrosion cracking in slow strain rate tests for sensitized and solution annealed 304 stainless steel at 288℃. Time-series analysis showed variations in the signature of the current density series due to transgranular stress corrosion cracking (TGSCC) and intergranular stress corrosion cracking (IGSCC).