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A New Ag~+-5-Phenyltetrazole Framework Incorporated Keggin Anions Showing Photocatalytic Activity

机译:新型掺有Keggin阴离子的Ag〜+ -5-苯基四唑骨架显示光催化活性

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摘要

Two new Ag~+-5-Phenyltetrazole framework incorporating Keggin anions, [Ag_8L_5](PW_(12)O_(40)) • (H_2O)_(13) and [Ag_8L_5](PMo_(12)O_(40)) • (H_2O)_(10), have been synthesized and characterized by elemental analysis and single crystal X-ray diffraction. The Keggin anions located at the voids of the framework. In addition, the luminescent property and photocatalytic activity of compounds are discussed in this paper. It shows a high activity towards decomposing the methyl orange (MO) solution under UV light.
机译:两种新的含Keggin阴离子的Ag〜+ -5-苯基四唑骨架[Ag_8L_5](PW_(12)O_(40))•(H_2O)_(13)和[Ag_8L_5](PMo_(12)O_(40))• (H_2O)_(10)已通过元素分析和单晶X射线衍射合成并表征。 Keggin阴离子位于骨架的空隙处。此外,本文还讨论了化合物的发光性能和光催化活性。它在紫外光下表现出很高的分解甲基橙(MO)溶液的活性。

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  • 来源
    《Materials Focus》 |2015年第1期|37-43|共7页
  • 作者单位

    Department of General Surgery, The First Hospital Jilin University, Changchun, 130021, P. R. China;

    Changchun University of Science and Technology, School of Chemistry and Environmental Engineering, Changchun 130022, P. R. China;

    Department of General Surgery, The First Hospital Jilin University, Changchun, 130021, P. R. China;

    Department of General Surgery, The First Hospital Jilin University, Changchun, 130021, P. R. China;

    Department of General Surgery, The First Hospital Jilin University, Changchun, 130021, P. R. China;

    Department of General Surgery, The First Hospital Jilin University, Changchun, 130021, P. R. China;

    Changchun University of Science and Technology, School of Chemistry and Environmental Engineering, Changchun 130022, P. R. China;

    Department of General Surgery, The First Hospital Jilin University, Changchun, 130021, P. R. China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Polyoxometalates; Ag; Keggin; Luminescent; Photocatalytic;

    机译:多金属氧酸盐;银凯金发光;光催化;

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