Delignification Mechanism During High-Boiling Solvent Pulping.Ⅳ. Effect of a Reducing Sugar on the Degradation of Guaiacylglycerol-β-guaiacyl Ether

摘要

A phenolic β-O-4 type lignin model compound, guaiacylglycerol-β-guaiacyl ether was treated with 70wt% aqueous 1, 3-butanediol solution in the presence of glucose at 160-200℃ to investigate the effect of reducing sugars on the degradation of lignin during high-boiling solvent (HBS) pulping. Addition of glucose increased the formation of guaiacol, coniferyl alcohol, and its γ-ethers, and decreased the formation of radical coupling compounds dramatically. These results suggest that reducing sugars may stabilize phenoxy radicals formed by homolysis of phenolic β-ethers. The kinetic studies also revealed that the disappearance of the β-ether model compound was enhanced substantially by the presence of glucose, which suggests that in addition to homolysis of the β-ether, a reducing sugar-assisted β-ether cleavage may be involved under the conditions used.