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Synthesis of CuPt Nanorod Catalysts with Tunable Lengths

机译:可调长度的CuPt纳米棒催化剂的合成

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摘要

Pt and Pt-containing alloys are important industrial catalysts and have many interesting properties and practical applications, particularly as nanoparticles. For example, Pt nanoparticles are efficient catalysts for CO oxidation and steam reforming reactions. Pt-M alloys (M = Fe, Co, Ni) have also been found to exhibit useful magnetic properties. From a catalysis perspective, Pt is expensive, and it is usually poisoned by CO, C, or S. This results in the blocking of active sites, reducing over time their catalytic efficacy. The ability to create bi- or trimetallic Pt-based nanoma-terials may prove to be a useful route for reducing the overall cost of the catalyst while retaining desirable catalytic properties and also affording a decrease in susceptibility to poisoning.
机译:Pt和含Pt合金是重要的工业催化剂,具有许多有趣的特性和实际应用,尤其是作为纳米粒子。例如,Pt纳米颗粒是用于CO氧化和蒸汽重整反应的有效催化剂。还发现Pt-M合金(M = Fe,Co,Ni)具有有用的磁性能。从催化的角度看,Pt价格昂贵,通常会被CO,C或S毒化。这会导致活性位点的封闭,并随着时间的推移降低其催化功效。产生双金属或三金属基于Pt的纳米材料的能力可能被证明是减少催化剂的总成本,同时保持理想的催化性能,并降低了中毒敏感性的有用途径。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2009年第16期|5720-5721|共2页
  • 作者单位

    Department of Chemistry, Texas A&M University, College Station, Texas 77842;

    Department of Chemistry, Texas A&M University, College Station, Texas 77842;

    Department of Chemistry and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802;

    Department of Chemistry, Texas A&M University, College Station, Texas 77842;

    Department of Chemistry, Texas A&M University, College Station, Texas 77842;

    Department of Chemistry, Texas A&M University, College Station, Texas 77842;

    Department of Chemistry, Texas A&M University, College Station, Texas 77842 Department of Chemistry and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
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