Magnetic Transition and Long-Time Relaxation Behavior Induced by Selective Injection of Guest Molecules into Clathrate Hydrates

摘要

Versatile nanostructures, including metal-organic frameworks and carbon-based materials, have been designed and synthesized for specific targets of material science and engineering. More significantly, several recent studies have reported the adsorption of magnetic molecules on a nanostructured surface and highlighted the unusual magnetic properties of these arrangements. The unique inclusion and coupling phenomena of gaseous magnetic guest molecules into low-dimensional microphases of nanostructured surfaces have been detected in the configurations of cages, tubes, and wires with the aim of controlling the properties of the material, including its magnetism or reactivity, thereby creating unusual and discrete magnetic patterns.