Nanospheres of a New Intermetallic FeSn_5 Phase: Synthesis, Magnetic Properties and Anode Performance in Li-ion Batteries

摘要

We synthesized monodisperse nanospheres of an intermetallic FeSns phase via a nanocrystal-conversion protocol using preformed Sn nanospheres as templates. This tetragonal phase in P4/mcc space group, along with the defect structure Fe_0.74Sn_s of our nanospheres, has been resolved by synchrotron X-ray diffraction and Rietveld refinement. Importantly, FeSn5, which is not yet established in the Fe-Sn phase diagram, exhibits a quasi-one dimensional crystal structure along the c-axis, thus leading to interesting anisotropic thermal expansion and magnetic properties. Magnetization measurements indicate that nanospheres are super paramagnetic above the blocking temperature T_B =300 K, which is associated with the higher magnetocrystalline anisotropy constant K - 3.33 kJ m~(-3).The combination of the magnetization measurements and first-principles density functional theory calculations reveals the canted antiferromagnetic nature with significant spin fluctuation in lattice a-b plane. The low Fe concentration also leads Fe0 74Sn5 to enhanced capacity as an anode in Li ion batteries.