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首页> 外文期刊>Journal of the American Chemical Society >Dopant-Free Hole-Transporting Material with a C_(3h) Symmetrical Truxene Core for Highly Efficient Perovskite Solar Cells
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Dopant-Free Hole-Transporting Material with a C_(3h) Symmetrical Truxene Core for Highly Efficient Perovskite Solar Cells

机译：具有C_（3h）对称Tru烯芯的无掺杂空穴传输材料，用于高效钙钛矿太阳能电池

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摘要

Herein we present a new structural design of hole-transporting material, Trux-OMeTAD, which consists of a C_(3h) Truxene-core with arylamine terminals and hexyl side-chains. This planar, rigid, and fully conjugated molecule exhibits excellent hole mobility and desired surface energy to the perovskite uplayer. Perovskite solar cells fabricated using the p-i-n architecture with Trux-OMeTAD as the p-layer, show a high PCE of 18.6% with minimal hysteresis.
机译：本文中，我们介绍了一种新型的空穴传输材料Trux-OMeTAD的结构设计，该结构由具有芳基胺末端和己基侧链的C_（3h）Truxene核组成。这种平面的，刚性的和完全共轭的分子对钙钛矿上层具有优异的空穴迁移率和所需的表面能。使用具有Trux-OMeTAD作为p层的p-i-n架构制造的钙钛矿太阳能电池显示出18.6％的高PCE，并具有最小的磁滞现象。

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  • 来源
    《Journal of the American Chemical Society》 |2016年第8期|2528-2531|共4页
  • 作者

    Chuyi Huang; Weifei Fu; Chang-Zhi Li; Zhongqiang Zhang; Weiming Qiu; Minmin Shi; Paul Heremans; Alex K.-Y. Jen; Hongzheng Chen;

  • 作者单位

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;

    Imec, Kapeldreef 75, 3001 Heverlee, Belgium;

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;

    Imec, Kapeldreef 75, 3001 Heverlee, Belgium;

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China, Department of Materials Science & Engineering, University of Washington, Seattle, Washington 98195, United States;

    MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;

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