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Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions

机译:中性条件下镍催化的酮和有机硼试剂直接合成芳基烯烃

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摘要

Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins direcdy. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.
机译:镍催化将芳基硼试剂加到酮中会导致芳基烯烃脱除。中性条件允许存在醇,酚和丙二酸酯的酸性质子,并且还容许脆弱的结构。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2017年第17期|6086-6089|共4页
  • 作者单位

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, SPMS-CBC-06-03, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, SPMS-CBC-06-03, Singapore 637371, Singapore;

    Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, SPMS-CBC-06-03, Singapore 637371, Singapore;

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  • 原文格式 PDF
  • 正文语种 eng
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  • 入库时间 2022-08-18 03:07:57

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