Carbothermal synthesis of ultra-fine zirconium carbide powders using inorganic precursors via sol–gel method

摘要

Ultra-fine zirconium carbide (ZrC) powders have been synthesized by carbothermal reduction reactions using inorganic precursors zirconium oxychloride (ZrOCl2 · 8H2O) as sources of zirconium and phenolic resin as the carbon source. The reactions were substantially completed at relatively lower temperatures (～1400 °C/1 h) and the synthesized powders had a small average crystallite size (<200 nm) and a large specific area (54 m2/g). The oxygen content of the powder synthesized at 1400 °C/1 h was less than 1.0 wt%. The thermodynamic change process in the ZrO2–C system and the synthesis mechanism were studied.